- Chemical NameMETHYL JASMONATE
- CAS No. 1211-29-6
- Contact UsInquiry
Factory Supply Industrial Grade METHYL JASMONATE 1211-29-6 with Best Price
- Molecular Formula:C13H20O3
- Molecular Weight:224.3
- Refractive Index:n20/D 1.474(lit.)
- Boiling Point:302.9 °C at 760mmHg
- Flash Point:128.6 °C
- PSA：43.37000
- Density:1.003 g/cm3
- LogP:2.50110
METHYL JASMONATE(Cas 1211-29-6) Usage
|
Trade name |
Jasmoneige? (Nippon Zeon), Splendione? (Firmenich) |
|
Synthesis |
Can be isolated from jasmine oil; synthetically it can be prepared (probably in the trans-form) from muconic acid via the methyl-3-oxo-cyclopentyl acetate |
|
Definition |
ChEBI: A jasmonate ester that is the methyl ester of jasmonic acid. |
|
Aroma threshold values |
Detection: 5.7 ppm |
|
Taste threshold values |
Taste characteristics at 15 ppm: floral, fruity, green, waxy, seedy and melon-like |
InChI:InChI=1S/C13H20O3/c1-3-4-5-6-11-10(7-8-12(11)14)9-13(15)16-2/h4-5,10-11H,3,6-9H2,1-2H3
1211-29-6 Relevant articles
Lipase-catalyzed preparation of both enantiomers of methyl jasmonate
Kiyota, Hiromasa,Higashi, Emi,Koike, Takanori,Oritani, Takayuki
, p. 1035 - 1038 (2001)
Preparation of both enantiomeric methyl ...
COMPARISONS OF VARIOUS BIOLOGICAL ACTIVITIES OF STEREOISOMERS OF METHYL JASMONATE
Koda, Yasunori,Kikuta, Yoshio,Kitahara, Takeshi,Nishi, Tsunehiro,Mori, Kenji
, p. 1111 - 1114 (1992)
Stereoisomers of methyl jasmonate (JA-Me...
Identification of jasmonic acid and abscisic acid as senescencepromoting substances from Cleyera ochnacea DC
Ueda,Kato
, p. 1975 - 1976 (1982)
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Enantioselective synthesis of (-)-methyl jasmonate and (+)-methyl epijasmonate
Roth, Gerald J.,Kirschbaum, Stephan,Bestmann, Hans Jürgen
, p. 618 - 620 (1997)
An efficient and flexible enantioselecti...
Investigation of synthetic lipase and its use in transesterification reactions
Kecili, Rustem,Say, Rdvan,Ers?z, Arzu,Hür, Deniz,Denizli, Adil
body text, p. 1981 - 1984 (2012/06/29)
A novel synthetic polymer selective for ...
Stereoselective synthesis of epi-jasmonic acid, tuberonic acid, and 12-oxo-PDA
Nonaka, Hisato,Ogawa, Narihito,Maeda, Noriaki,Wang, Yong-Gang,Kobayashi, Yuichi
experimental part, p. 5212 - 5223 (2010/12/25)
epi-Jasmonic acid (epi-JA) and tuberonic...
Asymmetric total synthesis of enantiopure (-)-methyl jasmonate via catalytic asymmetric intramolecular cyclopropanation of α-diazo-β-keto sulfone
Takeda, Hiroyuki,Watanabe, Hideaki,Nakada, Masahisa
, p. 8054 - 8063 (2007/10/03)
A new asymmetric total synthesis of enan...
Behaviour of monocomplexed 1,4-diynes in the Khand reaction and use of ethylene equivalent techniques in a convenient route to tritium-labelled methyl jasmonate
Kerr, William J.,McLaughlin, Mark,Pauson, Peter L.
, p. 118 - 124 (2007/10/03)
1,2-Complexed hexacarbonyl(hepta-1,4-diy...
1211-29-6 Process route
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29119-47-9,114029-37-7,37435-88-4,82423-75-4,83648-24-2,131063-53-1
(2R*,3S*)-3-methoxycarbonylmethyl-2-(2-pentynyl)cyclopentanone
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-
1211-29-6,20073-13-6,39924-52-2,42536-97-0,53369-26-9,62653-86-5,78609-06-0,93452-02-9,95722-42-2,109959-42-4,136233-36-8
methyl jasmonate
| Conditions | Yield |
|---|---|
|
With
hydrogen;
Lindlar's catalyst;
In
toluene;
at 20 ℃;
for 3h;
|
99% |
|
With
quinoline; hydrogen;
palladium on barium sulfate;
In
methanol;
|
95% |
|
With
hydrogen;
Lindlar's catalyst;
In
methanol;
for 2h;
under 760 Torr;
Ambient temperature;
|
93% |
|
With
hydrogen;
Lindlar's catalyst;
|
|
|
Lindlar's catalyst;
In
hexane;
|
|
|
With
hydrogen;
quinoline; palladium on barium sulfate;
In
Petroleum ether;
|
|
|
With
hydrogen;
Pd-BaSO4;
In
pyridine;
for 1.5h;
Yield given;
Ambient temperature;
|
-
-
73205-94-4
Methyl 6-oxo-2(E)-dodecen-9-ynoate
-
-
1211-29-6,20073-13-6,39924-52-2,42536-97-0,53369-26-9,62653-86-5,78609-06-0,93452-02-9,95722-42-2,109959-42-4,136233-36-8
methyl jasmonate
| Conditions | Yield |
|---|---|
|
With
quinoline; hydrogen;
Lindlar's catalyst;
In
methanol;
for 1h;
under 3677.5 Torr;
Ambient temperature;
|
95% |
|
Multi-step reaction with 2 steps
1: 1.) pyrrolidine / 1.) TiCl4 / 1.) benzene, reflux, 6 h, 2.) xylene, reflux, 20 h
2: 93 percent / H2 / Lindlar catalyst / methanol / 2 h / 760 Torr / Ambient temperature
With
pyrrolidine; hydrogen;
Lindlar's catalyst; titanium tetrachloride;
In
methanol;
|
1211-29-6 Upstream products
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55254-73-4
2-methoxycarbonyl-3-<(methoxycarbonyl)methyl>-2-<(Z)-2-pentenyl>cyclopentanone
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29119-47-9
(2R*,3S*)-3-methoxycarbonylmethyl-2-(2-pentynyl)cyclopentanone
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186581-53-3
diazomethane
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3572-65-4
jasmonic acid
1211-29-6 Downstream products
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2570-03-8
(+/-)-methyl trans-dihydrojasmonate
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3572-65-4
jasmonic acid
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1211-29-6
methyl (2-(2-pent-2Z-enyl)-3-oxocyclopentyl)acetate
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6894-38-8
jasmonic acid