- Chemical Name 4-NITROPHENYLSULFUR PENTAFLUORIDE
- CAS No. 2613-27-6
- Contact Us Inquiry
Reputable manufacturer supply 4-NITROPHENYLSULFUR PENTAFLUORIDE 2613-27-6 in stock with high standard
- Molecular Formula: C6H4 F5 N O2 S
- Molecular Weight: 249.161
- Melting Point: 38 °C
- Refractive Index: 1.4729
- Boiling Point: 76-77°C 12mm
- Flash Point: °C
- PSA： 71.12000
- Density: g/cm3
- LogP: 4.77540
4-NITROPHENYLSULFUR PENTAFLUORIDE(Cas 2613-27-6) Usage
|
General Description |
4-Nitrophenylsulfur pentafluoride is a chemical compound with the molecular formula C6H4F5NO2S. It is an organofluorine compound that is commonly used as a fluorinating agent in organic synthesis. This molecule is a powerful electrophilic fluorinating reagent that can be used to introduce fluorine atoms into organic compounds, particularly aromatic and heteroaromatic compounds. It is often utilized in the synthesis of pharmaceuticals, agrochemicals, and other fine chemicals. 4-Nitrophenylsulfur pentafluoride is known for its high reactivity and selectivity in fluorination reactions, making it a valuable tool in the field of organic chemistry. However, it should be handled with caution due to its potential toxicity and corrosiveness. |
InChI:InChI=1/C6H4F5NO2S/c7-15(8,9,10,11)6-3-1-5(2-4-6)12(13)14/h1-4H
2613-27-6 Relevant articles
AgBF4-Mediated Chlorine-Fluorine Exchange Fluorination for the Synthesis of Pentafluorosulfanyl (Hetero)arenes
Tanagawa, Kazuhiro,Zhao, Zhengyu,Saito, Norimichi,Shibata, Norio
supporting information, p. 1682 - 1684 (2021/07/19)
We report a new protocol to form pentafl...
Enhanced preparation of aryl and heteryl sulfur pentafluorides using mercury (II) oxide - hydrogen fluoride media as a fluorinating reagent
Fetyukhin, Volodymyr N.,Guzyr, Olexandr I.,Kozel, Volodymyr N.,Rozhenko, Olexandr B.,Rusanov, Eduard B.,Shermolovich, Yuriy G.
, (2020/09/18)
We developed enhanced method for low tem...
METHOD OF PRODUCING PENTAFLUOROSULFANYL AROMATIC COMPOUND
-
Paragraph 0049-0052, (2020/03/09)
A method of producing a pentafluorosulfa...
Preparation of (Pentafluorosulfanyl)benzenes by Direct Fluorination of Diaryldisulfides: Synthetic Approach and Mechanistic Aspects
Ajenjo, Javier,Klepetá?ová, Blanka,Greenhall, Martin,Bím, Daniel,Culka, Martin,Rulí?ek, Lubomír,Beier, Petr
supporting information, p. 11375 - 11382 (2019/08/20)
Direct fluorination of ortho-, meta- and...
2613-27-6 Process route
-
-
1526-28-9
4-nitrophenylsulphur trifluoride
-
-
2613-27-6
1-nitro-4-(pentafluorosulfanyl)benzene
| Conditions | Yield |
|---|---|
|
With
fluorine;
In
acetonitrile;
at 20 ℃;
|
60%
|
|
With
fluorine;
Ambient temperature;
|
44%
|
|
With
bis(fluoroxy)methane;
In
acetonitrile;
at -20 - 20 ℃;
|
|
|
With
fluorine; cesium fluoride;
In
acetonitrile;
at -30 - -25 ℃;
|
|
|
With
potassium fluoride; bis(fluoroxy)methane;
In
acetonitrile;
at -15 ℃;
|
-
-
4-nitrophenyltetrafluoro-λ6 -sulfanyl chloride
-
-
2613-27-6
1-nitro-4-(pentafluorosulfanyl)benzene
| Conditions | Yield |
|---|---|
|
With
hydrogen fluoride; mercury(II) oxide;
at -30 - 20 ℃;
Inert atmosphere;
Sealed tube;
|
81%
|
|
With
iodine pentafluoride;
In
neat (no solvent);
at 65 ℃;
for 14h;
Glovebox;
Inert atmosphere;
|
75%
|
|
With
silver carbonate;
at 70 ℃;
Inert atmosphere;
Glovebox;
|
66%
|
|
With
zinc(II) fluoride;
at 150 ℃;
for 72h;
Inert atmosphere;
|
36%
|
|
With
silver tetrafluoroborate;
In
dichloromethane;
at 20 ℃;
for 14h;
Inert atmosphere;
|
189.9 mg
|
2613-27-6 Upstream products
-
1526-28-9
4-nitrophenylsulphur trifluoride
-
100-32-3
di(p-nitrophenyl) disulfide
-
937-32-6
4-nitrobenzenesulfenyl chloride
-
1849-36-1
para-nitrobenzenethiol
2613-27-6 Downstream products
-
2993-24-0
4-(pentafluorosulfanyl)aniline
-
774-93-6
1-bromo-4-pentafluorosulfanylbenzene
-
5310-68-9
(4-chlorophenyl)pentafluoro-λ6 -sulfane
-
401892-85-1
4-(pentafluorosulfaneyl)benzonitrile
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